Glassy dynamics of kinetically constrained models
نویسندگان
چکیده
We review the use of kinetically constrained models (KCMs) for the study of dynamics in glassy systems. The characteristic feature of KCMs is that they have trivial, often non-interacting, equilibrium behaviour but interesting slow dynamics due to restrictions on the allowed transitions between configurations. The basic question which KCMs ask is therefore howmuch glassy physics can be understood without an underlying ‘equilibrium glass transition’. After a brief review of glassy phenomenology, we describe the main model classes, which include spin-facilitated (Ising) models, constrained lattice gases, models inspired by cellular structures such as soap froths, models obtained via mappings from interacting systems without constraints, and finally related models such as urn, oscillator, tiling and needle models. We then describe the broad range of techniques that have been applied to KCMs, including exact solutions, adiabatic approximations, projection and mode-coupling techniques, diagrammatic approaches and mappings to quantum systems or effective models. Finally, we give a survey of the known results for the dynamics of KCMs both in and out of equilibrium, including topics such as relaxation time divergences and dynamical transitions, nonlinear relaxation, ageing and effective temperatures, cooperativity and dynamical heterogeneities, and finally non-equilibrium stationary states generated by external driving. We conclude with a discussion of open questions and possibilities for future work.
منابع مشابه
Spatial correlations in the relaxation of the Kob-Andersen model
– We describe spatio-temporal correlations and heterogeneities in a kinetically constrained glassy model, the Kob-Andersen model. The kinetic constraints of the model alone induce the existence of dynamic correlation lengths, that increase as the density ρ increases, in a way compatible with a double-exponential law. We characterize in detail the trapping time correlation length, the cooperativ...
متن کاملDecoupling of exchange and persistence times in atomistic models of glass formers.
With molecular dynamics simulations of a fluid mixture of classical particles interacting with pairwise additive Weeks-Chandler-Andersen potentials, we consider the time series of particle displacements and thereby determine the distributions for local persistence times and local exchange times. These basic characterizations of glassy dynamics are studied over a range of supercooled conditions ...
متن کاملDynamical arrest, tracer diffusion and Kinetically Constrained Lattice Gases
We analyze the tagged particle diffusion for kinetically constrained models for glassy systems. We present a method, focusing on the KobAndersen model as an example, which allows to prove lower and upper bounds for the self diffusion coefficient DS . This method leads to the exact density dependence of DS , at high density, for models with finite defects and to prove diffusivity, DS > 0, at any...
متن کاملRotational correlation and dynamic heterogeneity in a kinetically constrained lattice gas.
We study the dynamical heterogeneity and glassy dynamics in a kinetically constrained lattice-gas model which has both translational and rotational degrees of freedom. We find that the rotational relaxation time tracks the structural relaxation time as density is increased whereas the translational diffusion constant exhibits a strong decoupling. We investigate distributions of exchange and per...
متن کاملAgeing, dynamical heterogeneities and crystallization in the Biroli-Mezard model
– We discuss a number of essential dynamical features of the Biroli-Mezard model. We observe a dynamical slowing down which for high densities depends both on the observation time and on the age of the system. We relate this ageing behavior to the real space dynamics of the system, from which it is clear that the system initially gains mobility due to some essential initial restructuring. We di...
متن کامل